2016-

1.原著論文

2016
(86) “Catalytic one-pot synthesis of end-functionalized poly(9,9’-di-n-octyl-fluorene vinylene)s by acyclic diene metathesis (ADMET) polymerization using ruthenium-carbene catalysts”
T. Miyashita, K. Nomura
Macromolecules, 49, 518-526 (2016).

(87) “Copolymerizations of norbornene, tetracyclododecene with α-olefins by half-titanocene catalysts: Efficient synthesis of highly transparent, thermal resistance polymers”
W. Zhao, K. Nomura
Macromolecules, 49, 59-70 (2016).

(88) “Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP−palladium complex”
S. Changsu, A. Inagaki
Dalton Trans., 45, 1331-1334 (2016).

(89) “Synthesis of ultrahigh molecular weight polymers by homopolymerisation of higher α-olefins catalysed by aryloxo-modified half-titanocenes”
K. Nomura, S. Pengoubol, W. Apisuk
RSC Advances6, 16203-16207 (2016).

(90) “Efficient introduction of aromatic vinyl group by incorporation of divinylbiphenyl, p-divinylbenzene in syndiospecific styrene polymerization using aryloxo-modified half-titanocene catalysts”
W. Apisuk, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 54, 1902-1907 (2016).  Cover article

(91) “Synthesis and structural analysis of Zr-Al hetero-bimetallic complexes, [ZrX{(O-2,4-tBu2C6H2-6-CH2)3(μ2-O-2,4-tBu2-C6H2-6-CH2)}N][R2Al(μ2-OiPr)] [X = Cl, Et, iBu; R = Me, Et, iBu]. Unique reactivity of the iBu complex”
U. Tewasekson, K. Tsutsumi, K. Nomura
Organometallics, 35, 866-874 (2016).

(92) “Photocatalytic oxygenation of sulfide and alkenes by trinuclear ruthenium clusters”
S. Phungsripheng, K. Kozawa, M. Akita, A. Inagaki
Inorg. Chem., 55, 3750–3758 (2016).

(93) “Efficient synthesis of cyclic olefin copolymers with high glass transition temperatures by ethylene copolymerization with tetracyclododecene (TCD) using (tert-BuC5H4)TiCl2(N=CtBu2) – MAO catalyst”
W. Apisuk, H. Ito, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 54, 2662-2667 (2016).  Cover article

(94) “Synthesis of (imido)vanadium(V) dichloride complexes containing anionic N-heterocyclic carbenes that contain a weakly coordinating borate moiety: New MAO-free ethylene polymerization catalysts”
A. Igarashi, E. L. Kolychev, M. Tamm, K. Nomura
Organometallics, 35, 1778-1784 (2016).  Most Read Article

(95) “One-pot synthesis of end-functionalized conjugated polymers by combined acyclic diene metathesis (ADMET) polymerization with Wittig-type coupling”
T. Miyashita, A. Inagaki, K. Nomura
J. Jpn. Petrol. Inst., 59, 197-203 (2016). Special issue (invited submission).

(96) “Efficient norbornene (NBE) incorporation in ethylene/NBE copolymerization by half-titanocene catalysts containing chlorinated aryloxo ligands”
W. Zhao, Q. Yan, K. Tsutsumi, K. Nomura
Organometallics, 35, 1895-1905 (2016). (W. Zhao and Q. Yan: equal contribution as the first author)

(97) “Size dependence of [N]cycloparaphenylenes (N = 5–12) in electrochemical oxidation”
E. Kayahara, K. Fukayama, T. Nishinaga, S. Yamago
Chem. Asian. J., 11, 1793–1797 (2016).

(98) “Direct observation of the triplet metal-centered state in [Ru(bpy)3]2+ using time-resolved infrared spectroscopy”
T. Mukuta, S. Tanaka, A. Inagaki, S. Koshihara, K. Onda
Chem. Select, 1, 2802-2807 (2016).

(99) “Ring-opening metathesis polymerization of cyclic olefins by (arylimido)vanadium(V)-alkylidenes: Highly active, thermally robust cis specific polymerization”
X. Hou, K. Nomura
J. Am. Chem. Soc., 138, 11840–11849 (2016).

(100) “Synthesis of (imido)niobium(V)-alkylidene complexes that exhibit high catalytic activities for metathesis polymerization of cyclic olefins and internal alkynes”
K. Wised, K. Nomura
Organometallics (Communication), 35, 2773–2777 (2016).

(101) “Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts: Factors affecting the efficient MO conversion and the selectivity”
N. W. Awang, K. Tsutsumi, B. Huštáková, S. F. M. Yusoff, K. Nomura, B. M. Yamin
RSC Advances, 6, 100925-100930 (2016).

2017
(102) “Synthesis and structural analysis of niobium(V) complexes containing amine triphenolate ligands of the type, [NbCl(X)(O-2,4-R2C6H2-6-CH2)3N] (R = Me, tBu; X = Cl, CF3SO3), and their use in catalysis for ethylene polymerization”
T. Omiya, N. Srisupap, K. Wised, K. Tsutsumi, K. Nomura
Polyhedron, 125, 9-17 (2017). Special issue, Tridentate and tetradentate tripodal ligands (invited submission).

(103) “Synthesis of mono, di, and trinuclear rhodium diphosphine complexes containing light-harvesting fluorene backbones”
Y. Matsusaka, S. Shitaya, K. Nomura, A. Inagaki
Inorg. Chem. (Communications), 56, 1027-1030 (2017).

(104) “Synthesis of (adamantylimido)vanadium(V) dimethyl complex containing (2-anilidomethyl)pyridine ligand and selected reactions: Exploring the oxidation state of the catalytically active species in ethylene dimerization”
K. Nomura, T. Mitsudome, A. Igarashi, G. Nagai, K. Tsutsumi, T. Ina, T. Omiya, H. Takaya, S. Yamazoe
Organometallics, 36, 530-542 (2017).

(105) “Effects of end-groups on photophysical properties of poly(9,9-di-n-octyl-fluorene-2,7-vinylene)s linked with metalloporphyrins: Synthesis and time-resolved fluorescence spectroscopy”
Y. Fushimi, M. Koinuma, Y. Yasuda, K. Nomura, M. S. Asano
Macromolecules, 50, 1803-1814 (2017).

(106) “Macrocyclic oligothiophene with stereogenic [2.2]paracyclophane scaffolds: Chiroptical properties from π-transannular interactions”
M. Hasegawa, K. Kobayakawa, H. Matsuzawa, T. Nishinaga, T. Hirose, K. Sako, Y. Mazaki
Chem. Eur. J., 23, 3267–3271 (2017).

(107) “Synthesis of poly(arylene vinylene)s containing different end groups by combined acyclic diene metathesis polymerization with Wittig-type coupling”
T. Miyashita, M. Kunisawa, S. Sueki, K. Nomura
Angew. Chem. Int. Ed., 56, 5288-5293 (2017). (T. Miyashita and M. Kunisawa: equal contribution as the first author) Inside Backcover Article (Highlight)

(108) “ Cyclic π-expanded oligothiophehe 12-mers as semishape-persistent macrocycles”
M. Imamura, H. Shimizu, J. Yamakawa, H. Otani, T. Nishinaga, M. Iyoda
Heterocycles, 95, 380-389(2017).

(109) “Ring opening metathesis polymerization of norbornene or tetracyclododecene with cyclooctene by using (arylmido)vanadium(V)-alkylidene catalyst”
S. Chaimongkolkunasin, X. Hou, K. Nomura
J. Polym. Sci.: Part A: Polym. Chem.55, 3067-3074 (2017). Special issue, celebrating Prof. Grubbs 75th birthday.

(110) “Effect of Al cocatalyst in ethylene and ethylene/norbornene (Co)polymerization by (imido)vanadium dichloride complexes containing anionic N-heterocyclic carbenes having weakly coordinating borate moiety”
G. Nagai, T. Mitsudome, K. Tsutsumi, S. Sueki, T. Ina, M. Tamm, K. Nomura
J. Jpn. Petrol. Inst., 60, 256-262 (2017). Special issue (invited submission).

(111) “Synthesis and structural analysis of palladium(II) complexes containing neutral or anionic C2-symmetric bis(oxazoline) ligands: Effects of substituents in the 5 position”
K. Tsutsumi, K. Itagaki, K. Nomura
ACS Omega2, 3886-3990 (2017).

(112) “Stable Radical Cations and their pi-Dimers Prepared from Ethylene- and Propylene-3,4-dioxythiophene Co-oligomers: Combined Experimental and Theoretical Investigations”
T. Nishinaga, Y. Sotome
J. Org. Chem.82, 7245-7253 (2017).

(113) “Effects of terthiophene as the end-groups in triblock copolymers consisting of poly(fluorene vinylene) and oligo(phenylene vinylene): Time-resolved fluorescence and its anisotropy”
M. S. Asano, Y. Yasuda, D. Kagota, T. Haque, K. Nomura
J. Photochem. Photobiol. A: Chem., 349, 18-24 (2017).

(114) “Synthesis and structural analysis of aryloxo-modified trinuclear half-titanocenes, and their use as catalyst precursors for ethylene polymerisation”
Q. Yan, K. Tsutsumi, K. Nomura
RSC Adv.7, 41345-41358 (2017).

(115) “Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes”
S. Phungsripheng, M. Akita, A. Inagaki
Inorg. Chem.56, 12996-13006 (2017).

(116) “Cis Specific chain transfer ring-opening metathesis polymerization using a vanadium(V)-alkylidene catalyst for efficient synthesis of end-functionalized polymers”
K. Nomura, X. Hou
Organometallics (Communication)36, 4103-4106 (2017).

(117) “Vanadium NMR chemical shifts of (imido)Vanadium(V) dichloride complexes with imidazolin-2-iminato and imidazolidin-2-iminato ligands: A cooperation with quantum-chemical calculations and multiple linear regression analyses”
J. Yi, W. Yang, W.-H. Sun, K. Nomura, M. Hada
J. Phys. Chem. A121, 9099-9105 (2017).

(118) “Synthesis, structural analysis of (imido)vanadium dichloride complexes containing 2-(2’-benz-imidazolyl)pyridine ligands: Effect of Al cocatalyst for efficient ethylene (co)polymerization”
K. Nomura, M. Oshima, T. Mitsudome, H. Harakawa, P. Hao, K. Tsutsumi, G. Nagai, T. Ina, H. Takaya, W.-H. Sun, S. Yamazoe
ACS Omega2, 8660-8673 (2017).

2018
(119) “Non-radical light-controlled polymerization of styrene and vinyl ethers catalyzed by an iridium−palladium photocatalyst”
S. Kikuchi, K. Saito, M. Akita, A. Inagaki
Organometallics37(3), 359-366 (2018).

(120) “Ethylene copolymerization with 4-methylcyclohexene, 1-methylcyclopentene by half-titanocene catalysts: Effect of ligands and microstructural analysis of the copolymers”
H. Harakawa, S. Patamma, A. Boccia, L. Boggioni, D. Ferro, S. Losio, K Nomura, I. Tritto
Macromolecules51, 853-863 (2018).

(121) “Noticeable chiral center dependence of signs and magnitudes in circular dichroism (CD) and circularly polarized luminescence (CPL) spectra of all-trans poly(9,9-dialkyl-fluorene-2,7-vinylene)s bearing chiral alkyl side chains in solution, aggregates, and in thin films”
T. Yamada, K. Nomura, M. Fujiki
Macromolecules51(6), 2377-2387 (2018).

(122) “Facile, efficient synthesis of star shaped π-conjugated systems by combined olefin metathesis with Wittig-type coupling”
T. Fujio, T. Miwata, M. Takase, S. Sueki, K. Nomura
J. Chin. Chem. Soc., 65, 317-324 (2018).  中國化学会(台北)  Special issue, International Symposium on Catalysis and Fine Chemicals 2016 (C&FC2016)

(123) “A Saturn-like complex composed of macrocyclic oligothiophene and [60]fullerene: structure, stability, and photophysical properties in solution and the solid state”
H. Shimizu, K. H. Park, H. Otani, S. Aoyagi, T. Nishinaga, Y. Aso, D. Kim, M. Iyoda
Chem. Eur. J., 24, 3793-3801 (2018).

(124) “Terthiophene functionalized conjugated triarm polymers containing poly(fluorene-2,7-Vinylene) arms having different cores. Synthesis and their unique optical properties”
K. Nomura, T. Miwata, T. Shinozuka, M. Morita, Y. Geerts, M. Fujiki, M. S. Asano
ACS Omega3, 5052-5063 (2018).

(125) “Solution XAS analysis of various (imido)vanadium(V) dichloride complexes containing monodentate anionic ancillary donor ligands: Effect of aluminium cocatalyst in ethylene/norbornene (co)polymerization”
K. Nomura, K. Tsutsumi, G. Nagai, T. Omiya, T. Ina, S. Yamazoe, T. Mitsudome
J. Jpn. Petrol. Inst.61, 282-287 (2018). Special issue (invited submission).

(126) “Synthesis of di-and trinuclear iridium polyhydride complex surrounded by light-absorbing ligands”
S. Shitaya, K. Nomura, A. Inagaki
Dalton Trans.47, 12046-12050 (2018).

(127) “Synthesis of (arylmido)niobium(V) complexes containing ketimide, phenoxide ligands, and some reactions with phenols, alcohols”
N. Srisupap, K. Wised, K. Tsutsumi, K. Nomura
ACS Omega, 3, 6166-6181 (2018).

(128) “Antiaromaticity of planar bisdehydro[12]- and tetrakisdehydro[16]-annulenes fused with dithieno[3,4-b:3’,4’-d]thiophenes”
T. Nishinaga, S. Shiroma, M. Hasegawa
Org. Lett., 20, 3426–3429 (2018).

(129) “Chemical stability of the 5-mesityl-5”-(nitronylnitroxide)-2,2′:5′,2”-ter(3,4-ethylenedioxythiophene) radical cation”
T. Tahara, S. Suzuki, M. Kozaki, T. Nishinaga, K. Okada
Bull. Chem. Soc., 19, 1193-1195 (2018).

(130) “Radical cation π-dimers of conjugated oligomers as molecular wires: An analysis based on nitronyl nitroxide spin labels”
T. Nishinaga, Y. Kanzaki, D. Shiomi, K. Matsuda, S. Suzuki, K. Okada
Chem. Eur. J., 24, 11717-11728 (2018).

(131) “(Arylimido)vanadium(V)-alkylidenes containing chlorinated phenoxy ligands: Thermally robust, highly active catalyst in ring-opening metathesis polymerization of cyclic olefins”
S. Chaimongkolkunasin, K. Nomura
Organometallics, 37, 2064-2074 (2018).

(132) “Interaction between the end groups and the main chain of conjugated polymers by time-resolved EPR and fluorescence spectroscopy”
M. S. Asano, S. Hashimoto, T. Shinozuka, Y. Fushimi, K. Nomura
Molecular Physics, accepted (2018).

(133) “One-pot synthesis of end-functionalised soluble star-shaped polymers by living ring-opening metathesis polymerisation using molybdenum-alkylidene catalyst”
Z. Sun, K. Nomura
RSC Adv.8, 27703-27708 (2018).

(134) “Efficient conversion of renewable unsaturated fatty acid methyl esters by cross metathesis with eugenol”
D. Le, C. Samart, K. Tsutsumi, K. Nomura, S. Kongparakul
ACS Omega3, 11041-11049 (2018).

(135) “Facile in situ generation of highly active (arylimido)vanadium(V)-alkylidene catalysts for ring-opening metathesis polymerization (ROMP) of cyclic olefins by immediate phenoxy ligand exchange”
H. Hayashibara, X. Hou, K. Nomura
Chem. Commun.54, accepted (2018).

 

2.総説・解説
2016
(19) “配位・メタセシス重合の新展開と展望”
野村琴広
高分子, 65, 509-511 (2016). 依頼

(20) “Design of efficient molecular catalysts for synthesis of cyclic olefin copolymers (COC) by copolymerization of ethylene, α-olefins with norbornene, tetracyclododecene”
W. Zhao, K. Nomura
Catalysts, 6, 175 (2016). Mini Review, Invited submission.

2017
(21) “Synthesis of vanadium-alkylidene complexes and their use as catalysts for ring opening metathesis polymerization”
K. Nomura, X. Hou,
Dalton Trans., 46, 12-24 (2017). Perspective, Invited submission. Cover article 

(22) “クロスカップリング反応の現状と展望”
野村琴広
工業材料, 65, 53-56 (2017). 特集号 “進化を続ける触媒技術の現状と今後を展望する” 依頼

(23) “Acyclic diene metathesis polymerization: Useful method for precise synthesis of defect-free rnd-functionalized poly(arylene vinylene)s”
T. Haque, K. Nomura
Green Sustain. Chem., 7, 1-19 (2017). Mini Review, Invited submission.

(24) “オレフィンメタセシス化学の最近の進展ーより高活性かつ緻密な反応制御を可能とする触媒開発”
野村琴広
化学, 72, 70-71(2017).

2018
(25) “高性能分子触媒が先導する新規オレフィン系高分子機能材料の創製”
野村琴広
ペトロテック, 41(1), 20-23 (2018).

(26) “Olefin metathesis polymerization: Some recent developments in the precise polymerizations for synthesis of advanced materials (by ROMP, ADMET)”
Y. Chen, M. M. Abdellatif, K. Nomura
Tetrahedron74, 619-643 (2018). Invited submission.

(27) “Solution XAS analysis for exploring the active species in homogeneous vanadium complex catalysis”
K. Nomura, T. Mitsudome, K. Tsutsumi, S. Yamazoe
J. Phys. Soc. Jpn., 87, 061014 (2018). Invited submission.

(28) “高性能オレフィン重合触媒の設計・創製:チタン及びバナジウム錯体触媒”
野村琴広
JACI ニュースレター, 66, 7d (2018).

(29) “高性能ハーフチタノセン錯体触媒による新規オレフィン系ポリマーの合成”
野村琴広
化学工業, 69, 409-413 (2018).

(30) “環状オレフィンの開環メタセシス重合に有効な高性能バナジウム錯体触媒の設計・創製”
野村琴広, 林原 瞳
高分子論文集, accepted (2018). 特集号:ポリオレフィン

(31) “定量的な末端官能基化を基盤とする集積型π共役ポリマーの精密合成と特異な光機能”
野村琴広
機能材料, 38(9), 29-36 (2018). 特集号:精密重合法によるポリマー材料の開発

 

3.著書
2016
(24) “Intrduction: Basic concepts and a brief histry of organic Redox systems”
T. Nishinaga, Organic redox systems: Synthesis, properties, and applications, T. Nishinaga Ed. Wiley, Hoboken NJ, 1-12 (2016).

(25) “Cationic oligothiophenes:p-Doped polythiophene models and application”
T. Nishinaga, Organic redox systems: Synthesis, properties, and applications, T. Nishinaga Ed. Wiley, Hoboken NJ, 383-410 (2016).

(26) “Acyclic diene metathesis (ADMET) polymerization for precise synthesis of defect-free conjugated polymers with well-defined chain ends”
T. Haque, K. Nomura
Feature Papers to Celebrate the Landmarks of Catalysts, K. Hohn (Ed.), MDPI AG, Basel, Switzerland, 124-143 (2016).

(27) “ハーフチタノセン触媒による環状オレフィン系共重合体の精密合成”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 10, 54-58 (2016).

2017
(28) “π共役系と色素”
T. Nishinaga
化学結合論 -分子の構造と機能, 橋本健朗 編著, 放送大学教育振興会, 149-162 (2017).

(29) “分子結晶と有機半導体”
T. Nishinaga
化学結合論 -分子の構造と機能, 橋本健朗 編著, 放送大学教育振興会, 163-177 (2017).

(30) “Synthesis and reaction chemistry of alkylidene complexes with titanium, zirconium, vanadium, and niobium: Effective catalysts for olefin metathesis polymerization and the other organic transformations”
S. Zhang, W. Zhang, K. Nomura
Adv. Organomet. Chem68, 93-136 (2017). Invited submission. (S.Z., W.Z.: equal contribution as the first author)

(31) “溶液X線吸収微細構造(XAFS)解析によるバナジウム触媒の構造解析: エチレン二量化・重合に有効なイミド配位バナジウム触媒を事例に”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 11, 58-62 (2017).

2018
(32) “Olefin polymerization by vanadium complex catalysts”
K. Nomura, X. Hou
Handbook of Transition Metal Polymerization Catalysts (2nd Ed.), Ray Hoff (Ed.), Wiley, 313-338 (2018).

(33) “バナジウム錯体触媒によるオレフィン重合・二量化反応 高性能分子触媒の創製と活性種解析”
野村琴広, 林原 瞳
触媒技術の動向と展望2018, 触媒学会(編), 84-96 (2018).

(34) “高性能分子触媒の設計とオレフィン系ポリマーの耐熱、透明性向上”
野村琴広
高耐熱樹脂の開発事例集, 技術情報協会(編), 258-266 (2018).

(35) “マテリアルサイエンス有機化学―基礎と機能材料への展開―第2版”
伊與田正彦, 横山 奏, 西長 亨
東京化学同人(2018).

(36) “オレフィンメタセシス重合”
野村琴広
(著書分担)基礎高分子科学, 高分子学会(編), 東京化学同人, 掲載予定.

(37) “溶液X線吸収微細構造(XAFS)解析によるバナジウム触媒の活性種解析:イミド配位バナジウム触媒によるエチレン重合”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 12, 掲載予定 (2018).

 

4.その他
2016
(10) “Asian Polyolefin Workshop 2015 (APO2015)”
野村琴広
触媒技術の動向と展望2016, 触媒学会(編), 287-288 (2016).

2017
(11) “時評: 第119回触媒討論会(首都大学東京)の開催に際して”
野村琴広
触媒, 59, 1 (2017).

(12) “Ligand effect in (imido)vanadium-alkylidene complexes for olefin metathesis polymerization”
S. Chaimongkolkunasin, X. Hou, K. Nomura
触媒(Catalysts and Catalysis), 59(B), 59-61 (2017).