2016-

1.原著論文

2016
(85) “Catalytic one-pot synthesis of end-functionalized poly(9,9’-di-n-octyl-fluorene vinylene)s by acyclic diene metathesis (ADMET) polymerization using ruthenium-carbene catalysts”
T. Miyashita, K. Nomura
Macromolecules, 49, 518-526 (2016).

(86) “Copolymerizations of norbornene, tetracyclododecene with α-olefins by half-titanocene catalysts: Efficient synthesis of highly transparent, thermal resistance polymers”
W. Zhao, K. Nomura
Macromolecules, 49, 59-70 (2016).

(87) “Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP−palladium complex”
S. Changsu, A. Inagaki
Dalton Trans., 45, 1331-1334 (2016).

(88) “Synthesis of ultrahigh molecular weight polymers by homopolymerisation of higher α-olefins catalysed by aryloxo-modified half-titanocenes”
K. Nomura, S. Pengoubol, W. Apisuk
RSC Advances6, 16203-16207 (2016).

(89) “Efficient introduction of aromatic vinyl group by incorporation of divinylbiphenyl, p-divinylbenzene in syndiospecific styrene polymerization using aryloxo-modified half-titanocene catalysts”
W. Apisuk, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 54, 1902-1907 (2016).  Cover article

(90) “Synthesis and structural analysis of Zr-Al hetero-bimetallic complexes, [ZrX{(O-2,4-tBu2C6H2-6-CH2)3(μ2-O-2,4-tBu2-C6H2-6-CH2)}N][R2Al(μ2-OiPr)] [X = Cl, Et, iBu; R = Me, Et, iBu]. Unique reactivity of the iBu complex”
U. Tewasekson, K. Tsutsumi, K. Nomura
Organometallics, 35, 866-874 (2016).

(91) “Photocatalytic oxygenation of sulfide and alkenes by trinuclear ruthenium clusters”
S. Phungsripheng, K. Kozawa, M. Akita, A. Inagaki
Inorg. Chem., 55, 3750–3758 (2016).

(92) “Efficient synthesis of cyclic olefin copolymers with high glass transition temperatures by ethylene copolymerization with tetracyclododecene (TCD) using (tert-BuC5H4)TiCl2(N=CtBu2) – MAO catalyst”
W. Apisuk, H. Ito, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 54, 2662-2667 (2016).  Cover article

(93) “Synthesis of (imido)vanadium(V) dichloride complexes containing anionic N-heterocyclic carbenes that contain a weakly coordinating borate moiety: New MAO-free ethylene polymerization catalysts”
A. Igarashi, E. L. Kolychev, M. Tamm, K. Nomura
Organometallics, 35, 1778-1784 (2016).  Most Read Article

(94) “One-pot synthesis of end-functionalized conjugated polymers by combined acyclic diene metathesis (ADMET) polymerization with Wittig-type coupling”
T. Miyashita, A. Inagaki, K. Nomura
J. Jpn. Petrol. Inst., 59, 197-203 (2016). Special issue (invited submission).

(95) “Efficient norbornene (NBE) incorporation in ethylene/NBE copolymerization by half-titanocene catalysts containing chlorinated aryloxo ligands”
W. Zhao, Q. Yan, K. Tsutsumi, K. Nomura
Organometallics, 35, 1895-1905 (2016). (W. Zhao and Q. Yan: equal contribution as the first author)

(96) “Size dependence of [N]cycloparaphenylenes (N = 5–12) in electrochemical oxidation”
E. Kayahara, K. Fukayama, T. Nishinaga, S. Yamago
Chem. Asian. J., 11, 1793–1797 (2016).

(97) “Direct observation of the triplet metal-centered state in [Ru(bpy)3]2+ using time-resolved infrared spectroscopy”
T. Mukuta, S. Tanaka, A. Inagaki, S. Koshihara, K. Onda
Chem. Select, 1, 2802-2807 (2016).

(98) “Ring-opening metathesis polymerization of cyclic olefins by (arylimido)vanadium(V)-alkylidenes: Highly active, thermally robust cis specific polymerization”
X. Hou, K. Nomura
J. Am. Chem. Soc., 138, 11840–11849 (2016).

(99) “Synthesis of (imido)niobium(V)-alkylidene complexes that exhibit high catalytic activities for metathesis polymerization of cyclic olefins and internal alkynes”
K. Wised, K. Nomura
Organometallics (Communication), 35, 2773–2777 (2016).

(100) “Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts: Factors affecting the efficient MO conversion and the selectivity”
N. W. Awang, K. Tsutsumi, B. Huštáková, S. F. M. Yusoff, K. Nomura, B. M. Yamin
RSC Advances, 6, 100925-100930 (2016).

(101) “Rhenium-catalyzed synthesis of 1,3-diiminoisoindolines via insertion of carbodiimides into a C−H bond of aromatic and heteroaromatic imidates”
Z. Wang, S. Sueki, M. Kanai, Y. Kuninobu
Org. Lett., 18, 2459-2462 (2016).

2017
(102) “Synthesis and structural analysis of niobium(V) complexes containing amine triphenolate ligands of the type, [NbCl(X)(O-2,4-R2C6H2-6-CH2)3N] (R = Me, tBu; X = Cl, CF3SO3), and their use in catalysis for ethylene polymerization”
T. Omiya, N. Srisupap, K. Wised, K. Tsutsumi, K. Nomura
Polyhedron, 125, 9-17 (2017). Special issue, Tridentate and tetradentate tripodal ligands (invited submission).

(103) “Synthesis of mono, di, and trinuclear rhodium diphosphine complexes containing light-harvesting fluorene backbones”
Y. Matsusaka, S. Shitaya, K. Nomura, A. Inagaki
Inorg. Chem. (Communications), 56, 1027-1030 (2017).

(104) “Synthesis of (adamantylimido)vanadium(V) dimethyl complex containing (2-anilidomethyl)pyridine ligand and selected reactions: Exploring the oxidation state of the catalytically active species in ethylene dimerization”
K. Nomura, T. Mitsudome, A. Igarashi, G. Nagai, K. Tsutsumi, T. Ina, T. Omiya, H. Takaya, S. Yamazoe
Organometallics, 36, 530-542 (2017).

(105) “Effects of end-groups on photophysical properties of poly(9,9-di-n-octyl-fluorene-2,7-vinylene)s linked with metalloporphyrins: Synthesis and time-resolved fluorescence spectroscopy”
Y. Fushimi, M. Koinuma, Y. Yasuda, K. Nomura, M. S. Asano
Macromolecules, 50, 1803-1814 (2017).

(106) “Macrocyclic oligothiophene with stereogenic [2.2]paracyclophane scaffolds: Chiroptical properties from π-transannular interactions”
M. Hasegawa, K. Kobayakawa, H. Matsuzawa, T. Nishinaga, T. Hirose, K. Sako, Y. Mazaki
Chem. Eur. J., 23, 3267–3271 (2017).

(107) “Synthesis of poly(arylene vinylene)s containing different end groups by combined acyclic diene metathesis polymerization with Wittig-type coupling”
T. Miyashita, M. Kunisawa, S. Sueki, K. Nomura
Angew. Chem. Int. Ed., 56, 5288-5293 (2017). (T. Miyashita and M. Kunisawa: equal contribution as the first author) Inside Backcover Article (Highlight)

(108) “ Cyclic π-expanded oligothiophehe 12-mers as semishape-persistent macrocycles”
M. Imamura, H. Shimizu, J. Yamakawa, H. Otani, T. Nishinaga, M. Iyoda
Heterocycles, 95, 380-389(2017).

(109) “Ring opening metathesis polymerization of norbornene or tetracyclododecene with cyclooctene by using (arylmido)vanadium(V)-alkylidene catalyst”
S. Chaimongkolkunasin, X. Hou, K. Nomura
J. Polym. Sci.: Part A: Polym. Chem.55, 3067-3074 (2017). Special issue, celebrating Prof. Grubbs 75th birthday.

(110) “Facile, efficient synthesis of star shaped π-conjugated systems by combined olefin metathesis with Wittig-type coupling”
T. Fujio, T. Miwata, M. Takase, S. Sueki, K. Nomura
J. Chin. Chem. Soc. ASAP.  中國化学会(台北)  Special issue, International Symposium on Catalysis and Fine Chemicals 2016 (C&FC2016)

(111) “Effect of Al cocatalyst in ethylene and ethylene/norbornene (Co)polymerization by (imido)vanadium dichloride complexes containing anionic N-heterocyclic carbenes having weakly coordinating borate moiety”
G. Nagai, T. Mitsudome, K. Tsutsumi, S. Sueki, T. Ina, M. Tamm, K. Nomura
J. Jpn. Petrol. Inst.60, 256-262 (2017). Special issue (invited submission).

(112) “Synthesis and structural analysis of palladium(II) complexes containing neutral or anionic C2-symmetric bis(oxazoline) ligands: Effects of substituents in the 5 position”
K. Tsutsumi, K. Itagaki, K. Nomura
ACS Omega2, 3886-3990 (2017).

(113) “Stable Radical Cations and their pi-Dimers Prepared from Ethylene- and Propylene-3,4-dioxythiophene Co-oligomers: Combined Experimental and Theoretical Investigations”
T. Nishinaga, Y. Sotome
J. Org. Chem.82, 7245-7253 (2017).

(114) “Effects of terthiophene as the end-groups in triblock copolymers consisting of poly(fluorene vinylene) and oligo(phenylene vinylene): Time-resolved fluorescence and its anisotropy”
M. S. Asano, Y. Yasuda, D. Kagota, T. Haque, K. Nomura
J. Photochem. Photobiol. A: Chem., 349, 18-24 (2017).

(115) “Synthesis and structural analysis of aryloxo-modified trinuclear half-titanocenes, and their use as catalyst precursors for ethylene polymerisation”
Q. Yan, K. Tsutsumi, K. Nomura
RSC Adv., 7, 41345-41358 (2017).

(116) “Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes”
S. Phungsripheng, M. Akita, A. Inagaki
Inorg. Chem., 56, 12996-13006 (2017).

(117) “Cis Specific chain transfer ring-opening metathesis polymerization using a vanadium(V)-alkylidene catalyst for efficient synthesis of end-functionalized polymers”
K. Nomura, X. Hou
Organometallics (Communication)36, 4103-4106 (2017).

(118) “Vanadium NMR chemical shifts of (imido)Vanadium(V) dichloride complexes with imidazolin-2-iminato and imidazolidin-2-iminato ligands: A cooperation with quantum-chemical calculations and multiple linear regression analyses”
J. Yi, W. Yang, W.-H. Sun, K. Nomura, M. Hada
J. Phys. Chem. A, 121, 9099-9105 (2017).

(119) “Synthesis, structural analysis of (imido)vanadium dichloride complexes containing 2-(2’-benz-imidazolyl)pyridine ligands: Effect of Al cocatalyst for efficient ethylene (co)polymerization”
K. Nomura, M. Oshima, T. Mitsudome, H. Harakawa, P. Hao, K. Tsutsumi, G. Nagai, T. Ina, H. Takaya, W.-H. Sun, S. Yamazoe
ACS Omega, 2, 8660-8673 (2017).

 

2.総説・解説

2016
(19) “配位・メタセシス重合の新展開と展望”
野村琴広
高分子, 65, 509-511 (2016). 依頼

(20) “Design of efficient molecular catalysts for synthesis of cyclic olefin copolymers (COC) by copolymerization of ethylene, α-olefins with norbornene, tetracyclododecene”
W. Zhao, K. Nomura
Catalysts, 6, 175 (2016). Mini Review, Invited submission.

2017
(21) “Synthesis of vanadium-alkylidene complexes and their use as catalysts for ring opening metathesis polymerization”
K. Nomura, X. Hou,
Dalton Trans., 46, 12-24 (2017). Perspective, Invited submission. Cover article 

(22) “クロスカップリング反応の現状と展望”
野村琴広
工業材料, 65, 53-56 (2017). 特集号 “進化を続ける触媒技術の現状と今後を展望する” 依頼

(23) “Acyclic diene metathesis polymerization: Useful method for precise synthesis of defect-free rnd-functionalized poly(arylene vinylene)s”
T. Haque, K. Nomura
Green Sustain. Chem., 7, 1-19 (2017). Mini Review, Invited submission.

(24) “オレフィンメタセシス化学の最近の進展ーより高活性かつ緻密な反応制御を可能とする触媒開発”
野村琴広
化学, 72, 70-71(2017).

(25) “高性能分子触媒が先導する新規オレフィン系高分子機能材料の創製”
野村琴広
ペトロテック, 掲載予定.

 

3.著書

2016
(24) “Intrduction: Basic concepts and a brief histry of organic Redox systems”
T. Nishinaga, Organic redox systems: Synthesis, properties, and applications, T. Nishinaga Ed. Wiley, Hoboken NJ, 1-12 (2016).

(25) “Cationic oligothiophenes:p-Doped polythiophene models and application”
T. Nishinaga, Organic redox systems: Synthesis, properties, and applications, T. Nishinaga Ed. Wiley, Hoboken NJ, 383-410 (2016).

(26) “Acyclic diene metathesis (ADMET) polymerization for precise synthesis of defect-free conjugated polymers with well-defined chain ends”
T. Haque, K. Nomura
Feature Papers to Celebrate the Landmarks of Catalysts, K. Hohn (Ed.), MDPI AG, Basel, Switzerland, pp. 124-143 (2016).

(27) “ハーフチタノセン触媒による環状オレフィン系共重合体の精密合成”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 10, 54-58 (2016).

(28) “Recent progress in synthesis of dihydropyridines”
S. Sueki, I. Shimizu
New Research on Dihydropyridines, J. Morales (Eds.), Nova Science Publishers, Inc., New York, USA, pp. 1-37 (2016).

2017
(29) “Olefin polymerization by vanadium complex catalysts”
K. Nomura, X. Hou
Handbook of Transition Metal Polymerization Catalysts (2nd Ed.), Ray Hoff (Ed.), Wiley, in press (2017).

(30) “π共役系と色素”
西長 亨
化学結合論 -分子の構造と機能, 橋本健朗 編著 放送大学教育振興会 149-162 (2017).

(31) “分子結晶と有機半導体”
西長 亨
化学結合論 -分子の構造と機能, 橋本健朗 編著 放送大学教育振興会 163-177 (2017).

(32) “Synthesis and reaction chemistry of alkylidene complexes with titanium, zirconium, vanadium, and niobium: Effective catalysts for olefin metathesis polymerization and the other organic transformations”
S. Zhang, W. Zhang, K. Nomura
Adv. Organomet. Chem, 68, 93-136 (2017). Invited submission. (S.Z., W.Z.: equal contribution as the first author)

(33) “溶液X線吸収微細構造(XAFS)解析によるバナジウム触媒の構造解析: エチレン二量化・重合に有効なイミド配位バナジウム触媒を事例に”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 11, 58-62 (2017).

 

4.その他

2016
(10) “Asian Polyolefin Workshop 2015 (APO2015)”
野村琴広
触媒技術の動向と展望2016,触媒学会(編), 287-288 (2016).

2017
(11) “時評: 第119回触媒討論会(首都大学東京)の開催に際して”
野村琴広
触媒,59, 1 (2017).

(12) “Ligand effect in (imido)vanadium-alkylidene complexes for olefin metathesis polymerization”
S. Chaimongkolkunasin, X. Hou, K. Nomura
触媒(Catalysts and Catalysis), 59(B), 59-61 (2017).