2013-2015

1.原著論文
2013
(38) “Ethylene polymerization using (imino)vanadium(V) dichloride complexes containing (anilido)methyl-pyridine, – quinoline ligands – halogenated Al alkyls catalyst systems”
A. Igarashi, W. Zhang, W.-H. Sun, K. Nomura
Catalysts, 3, 148-156 (2013).

(39) “Synthesis and structural analysis of (imido)vanadium(V) complexes containing chelate (anilido)methyl-imine ligands: Ligand effect in ethylene dimerization”
K. Nomura, A. Igarashi, S. Katao, W. Zhang, W.-H. Sun
Inorg. Chem, 52, 2607-2614 (2013).

(40) “Efficient ethylene/norbornene copolymerization by half-titanocenes containing imidazolin-2-iminato ligands – MAO catalyst systems”
W. Apisuk, A. G. Trambitas, B. Kitiyanan, M. Tamm, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 51, 2575-2580 (2013).

(41) “Efficient terpolymerization of ethylene and styrene with alfa-olefins by aryloxo modified half-titanocene-based catalysts – cocatalyst systems”
W. Apisuk, N. Suzuki, H.-J. Kim, D.-H. Kim, B. Kitiyanan, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 51, 2565-2574 (2013).

(42) “Introduction of reactive functionality by incorporation of divinylbiphenyl in ethylene copolymerization with styrene or 1-hexene using aryloxo-modified half-titanocenes – MAO catalysts”
W. Apisuk, B. Kitiyanan, H.-J. Kim, D.-H. Kim, K. Nomura
J. Polym. Sci. Part A: Polym. Chem., 51, 2581-2587 (2013). Inside front cover

(43) “Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(II)polypyridyl and naphthyl moieties”
K. Murata, M. Araki, A. Inagaki, M. Akita
Dalton Trans., 42(19), 6989-7001(2013).

(44) “Precise synthesis of end-functionalized oligo(2,5-dialkoxy-1,4-phenylene vinylene)s with controlled repeat units via combined olefin metathesis and Wittig-type coupling”
M. M. Abdellatif, K. Nomura
Org. Lett., 15, 1618-1621 (2013).

(45) “Solvent-induced crystalline state emission and multi chromism of a bent π-surface system composed of dibenzocyclooctatetraene units”
T. Nishiuchi, K. Tanaka, Y. Kuwatani, J. Sung, T. Nishinaga, D. Kim, M. Iyoda
Chem. Eur. J., 19, 4110-4116 (2013). Frontispiece

(46) “Steric control in the π-dimerization of oligothiophene radical cations annelated with bicyclo[2.2.2]octene units”
M. Tateno, M. Takase, M. Iyoda, K. Komatsu, T. Nishinaga
Chem. Eur. J., 19, 5457-5467 (2013).

(47) “Antiaromatic planar cyclooctatetraene: a strategy for developing ambipolar semiconductors for field effect transistors”
T. Nishinaga, T. Ohmae, K. Aita, M. Takase, M. Iyoda, T. Arai, Y. Kunugi
Chem. Commun., 49, 5354–5356 (2013). Inside front cover

(48) “Revelation of the photoactive species in the photocatalytic dimerization of α-methylstyrene by a dinuclear ruthenium-palladium complex”
K. Murata, A. Inagaki, M. Akita, J.-F. Halet, K. Costuas
Inorg. Chem., 52(14), 8030–8039 (2013).

(49) “Manganese(II) semiquinonato and manganese(III) catecholato complexes with tridentate ligand: modeling the substrate-binding state of manganese-dependent catechol dioxygenase and reactivity with molecular oxygen”
H. Komatsuzaki, A. Shiota, S. Hazawa, M. Itoh, N. Miyamura, N. Miki, Y. Takano, J. Nakazawa, A. Inagaki, M. Akita, S. Hikichi
Chem. Asian J., 8, 1115-1119 (2013).

(50) “Pyrrole-fused azacoronene family: The influence of replacement with dialkoxybenzenes on the optical and electronic properties in neutral and oxidized states”
M. Takase, T. Narita, W. Fujita, M. S. Asano, T. Nishinaga, H. Benten, K. Yoza, K. Müllen
J. Am. Chem. Soc., 135, 8031-8040 (2013).

(51) “Donor-acceptor segregated paracyclophanes composed of naphthobipyrrole and stacked fluoroarenes”
M. Takase, A. Inabe, Y. Sugawara, W. Fujita, T. Nishinaga, K. Nomura
Org. Lett., 15, 3202–3205 (2013).

(52) “Structure-dependent electronic natures of star-shaped oligothiophenes probed by ensemble and single-molecule spectroscopy”
H. Chung, T. Narita, J. Yang, P. Kim, M. Takase, M. Iyoda, D. Kim
Chem. Eur. J., 19, 9699-9709 (2013).

(53) “Synthesis, structural analysis of the hetero-bimetallic complexes MMe[(O-2,4-tBu2C6H2-6-CH2)2(μ2-O-2,4-tBu2C6H2-6-CH2)N][Me2Al(μ2-OiPr)] [M = Zr, Hf] and their use in catalysis for ethylene polymerization”
Y. Takii, A. Inagaki, K. Nomura
Dalton Trans., 42, 11632-11639 (2013).

(54) “Synthesis of binuclear phenoxyimino organoaluminum complexes and their use as the catalyst precursors for efficient ring-opening polymerisation of ε-caprolactone”
H.-L. Han, Y. Liu, J. Liu, K. Nomura, Y.-S. Li
Dalton Trans., 42, 12346-12353 (2013).

(55) “Dithieno[3,4-b:3’,4’-d]thiophene-annelated antiaromatic planar cyclooctatetraene with olefinic protons”
K. Aita, T. Ohmae, M. Takase, K. Nomura, H. Kimura, T. Nishinaga
Org. Lett., 15, 3522–3525 (2013).

(56) “Effect of substituents on the structure, stability, and π-dimerization of dithienylpyrrole radical cations”
T. Nishinaga, T. Kageyama, M. Koizumi, K. Ando, M. Takase, M. Iyoda
J. Org. Chem., 78, 9205–9213 (2013).

(57) “Precise synthesis of poly(fluorene vinylene)s capped with chromophores: Efficient fluorescent polymers modified by conjugation length and end-groups”
K. Takamizu, A. Inagaki, K. Nomura
ACS Macro Lett., 2, 980-984 (2013). Most Read Article

(58) “Precise one-pot synthesis of end-functionalized conjugated multi-block copolymers via combined olefin metathesis and Wittig-type coupling”
K. Nomura, T. Haque, T. Onuma, F. Hajjaj, M. S. Asano, A. Inagaki
Macromolecules, 46, 9563-9574 (2013).

2014
(59) “Synthesis and structural analysis of (imido)vanadium(V) dichloride complexes containing imidazolin-2-iminato- and imidazolidin-2-iminato ligands, and their use as catalyst precursors for ethylene (co)polymerization”
K. Nomura, B. K. Bahuleyan, S. Zhang, P. M. V. Sharma, S. Katao, A. Igarashi, A. Inagaki, M. Tamm
Inorg. Chem., 53, 607-623 (2014).

(60) “Synthesis of trinuclear Pd-Ru-Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region”
Y. Yasu, A. Inagaki, M. Akita
J. Organomet. Chem., 753, 48-54 (2014).

(61) “Synthesis of (imido)vanadium(V) complexes containing 8-(2,6-dimethylanilide)-5,6,7-trihydroquinoline ligands: Highly active catalyst pecursors for ethylene dimerization”
X.-Y. Tang, A. Igarashi, W.-H. Sun, A. Inagaki, J. Liu, W. Zhang, Y.-S. Li, K. Nomura
Organometallics, 33, 1053-1060 (2014). (X.-Y. Tang and A. Igarashi: euqal contribution as the first author) Most Read Article

(62) “Synthesis of highly conjugated dinuclear Ru complexes bridged by a novel N2-N3 ligand and their application in photocatalytic oxygenation of sulfides”
K. Kozawa, A. Inagaki, M. Akita
Chem. Lett., 43, 290-292 (2014).

(63) “Vibrational spectroscopy at the excited triplet state in [Ru(bpy)2(bpm)]2+ and [Ru(bpy)3]2+”
T. Mukuta, N. Fukazawa, K. Murata, A. Inagaki, M. Akita, S. Tanaka, S. Koshihara, K. Onda
Inorg. Chem., 53, 2481-2490 (2014).

(64) “Multifunctional π-expanded macrocyclicoligothiophene 6-mers and related macrocyclic oligomers”
M. Iyoda, K. Tanaka, H. Shimizu, M. Hasegawa, T. Nishinaga, T. Nishiuchi, Y.Kunugi, T. Ishida, H. Otani, H. Sato, K. Inukai, K. Tahara, Y. Tobe
J. Am. Chem. Soc., 136, 2389-2396 (2014).

(65) “Diradical character of benzo- and naphtho-annelatedthiophene–pyrrole mixed oligomer dications”
T. Kageyama, S. Uneme, M. Takase, K. Nomura, T. Nishinaga
Aust. J. Chem., 67, 722-728 (2014). Front Image

(66) “Vanadyl di(5-t-butyl-2-(aryliminomethyl)quinolin-8-olate): Synthesis, characterization and their ethylene (co-)polymerization”
Q. Yan, Z. Sun, W. Zhang, K. Nomura, W.-H. Sun
Macromol. Chem. Phys., 215, 1744-1752 (2014). Special issue (invited submission), Continuing Innovation in Polyolefin Catalysis and Materials, dedicated to Prof. Minoru Terano

(67) “Efficient terpolymerization of ethylene and styrene with 1,7-octadiene by aryloxo modified half-titanocenes – cocatalyst systems: Efficient introduction of the reactive functionality”
W. Apisuk, K. Nomura
Macromol. Chem. Phys., 215, 1785-1791 (2014). Special issue (invited submission), Continuing Innovation in Polyolefin Catalysis and Materials, dedicated to Prof. Minoru Terano

(68) “Synthesis of well-defined oligo(2,5-dialkoxy-1,4-phenylene vinylene)s by combined olefin metathesis and Wittig-type coupling: Effect of conjugation repeat units and end groups toward optical properties”
M. M. Abdellatif, S. Yorsaeng, A. Inagaki, K. Nomura
Macromol. Chem. Phys., 215, 1973-1983 (2014). Special issue (invited submission). Precision Polymers

(69) “Synthesis and Conductive Properties of Gold Nanoparticles Protected by Partially Bicyclo[2.2.2]octene-Annelated and Methylthio End-Capped Oligothiophene Thiolates”
M. Tateno, M. Takase, T. Nishinaga
Chem. Mater., 26, 3804–3810 (2014).

(70) “Synthesis of (adamantylmido)vanadium(V)-alkyl, alkylidene complex trapped with PMe3: Reactions of the alkylidene complexes with phenols”
K. Hatagami, K. Nomura
Organometallics, 33, 6585–6592 (2014). Editor’s Choice

(71) “Synthesis of (imido)vanadium(V)-alkyl and -alkylidene complexes containing imidazolidin-2-iminato ligands: Effect of imido ligand on ROMP and 1,2-C-H bond activation of benzene”
K. Nomura, B. K. Bahuleyan, K. Tsutsumi, A. Igarashi
Organometallics, 33, 6682–6691 (2014).

2015
(72) “Precise one-pot synthesis of fully conjugated end-functionalized star polymers containing poly(fluorene-2,7- vinylene) (PFV) arms”
K. Nomura, T. Haque, T. Miwata, A. Inagaki, K. Takamizu
Polym. Chem., 6, 380-388 (2015). Backside cover

(73) “Ethylene polymerisation and ethylene/norbornene copolymerisation by aryloxo-modified vanadium(V) complexes containing 2,6-difluoro-, dichloro-phenylimido complexes”
N. Diteepeng, X. Tang, X. Hou, Y.-S. Li, K. Phomphrai, K. Nomura
Dalton Trans., 44, 12273-12281 (2015). Special issue (invited submission). Earth abundant element compounds in homogeneous catalysis

(74) “Visible-light-controlled homo- and copolymerization of styrenes by bichromophoric Ir-Pd catalyst”
K. Murata, K. Saito, S. Kikuchi, M. Akita, A. Inagaki
Chem. Commun., 51, 5717-5720 (2015).

(75) “(Arylimido)vanadium(V)-alkylidene complexes containing fluorinated aryloxo, alkoxo ligands for fast living ring-opening metathesis polymerization (ROMP), Highly cis-specific ROMP”
X. Hou, K. Nomura
J. Am. Chem. Soc.137, 4662–4665 (2015).

(76) “Efficient Synthesis, Structure, and Complexation Studies of Electron-Donating Thiacalix[n]dithienothiophene”
R. Inoue, M. Hasegawa, T. Nishinaga, K. Yoza, Y. Mazaki
Angew. Chem. Int. Ed., 54, 2734–2738 (2015).

(77) “Synthesis, Structures, and Photophysical Properties of π-Expanded Oligothiophene 8-Mers and Their Saturn-like C60 Complexes”
H. Shimizu, J. D. Cojal González, M. Hasegawa, T. Nishinaga, T. Haque, M. Takase, H. Otani, J. P. Rabe, M. Iyoda
J. Am. Chem. Soc.137, 3877-3885 (2015).

(78) “Synthesis and structural analysis of half-titanocenes containing 1,3-imidazolidin-2-iminato ligands: Effect of ligand substituents in ethylene (co)polymerization”
K. Nomura, H. Fukuda, H. Matsuda, S. Katao, S. Patamma
J. Organomet. Chem., 798, 375-383 (2015). Special issue (invited submission). Metal-Catalyzed Polymerization of Olefins

(79) “Synthesis of titanium complexes containing amine triphenolate ligand of the type, [TiX{(O-2,4-R2C6H2)-6-CH2}3N], and the Ti-Al hetero-bimetallic complexes with AlMe3: Effect of terminal donor ligand in ethylene polymerization”
K. Nomura, U. Tewasekson, Y. Takii
Organometallics, 34, 3272-3281 (2015).

(80) “C-C Bond Forming Reductive Elimination from Diarylplatinum Complexes Driven by Visible-Light-Mediated Photoredox Reaction”
Y. Shiba, A. Inagaki, M. Akita
Organometallics, Organometallics, 34, 4844-4853 (2015).

(81) “Synthesis of half-titanocenes containing 1,3-imidazolidin-2-iminato ligands of type, Cp*TiCl2[1,3-R2(CH2N)2C=N]: Highly active catalyst precursors in ethylene (co)polymerisation”
K. Nomura, S. Patamma, H. Matsuda, S. Katao, K. Tsutsumi, H. Fukuda
RSC Advances, 5, 64503-64513 (2015).

(82) “Time-resolved fluorescence spectra in the end-functionalized conjugated triblock copolymers consisting of poly(fluorene vinylene) and oligo(phenylene vinylene): Proposal of dynamical distortion in the excited state”
M. Asano, D. Kagota, H. Tahmina, M. Koinuma, A. Inagaki, K. Nomura
Macromolecules, 48, 6233–6240 (2015).

(83) “Synthesis and structural analysis of tungsten-carbonyl dimers bridged with oligo(2,5-dialkoxy-1,4-phenylene vinylene)s through pyridine coordination”
S. Yorsaeng, K. Tsutsumi, B. Kitiyanan, K. Nomura
Dalton Trans., 44, 16728–16736 (2015). Backside Cover

(84) “Synthesis of well-defined oligo(2,5-dialkoxy-1,4-phenylene vinylene)s with chiral end groups: Unique helical aggregations induced by the chiral chain ends”
S. Yorsaeng, Y. Kato, K. Tsutsumi, A. Inagaki, B. Kitiyanan, M. Fujiki, K. Nomura
Chem. Eur. J., Commun., 21, 16764-16768 (2015).

 

2.総説・解説
2013
(12) “オレフィンメタセシスを利用した高分子機能材料の精密合成‐精密重合を基盤とした集積化機能材料の創製‐”
野村琴広, 高水賢治, 藤尾隆史
有機合成化学協会誌, 71, 2-13 (2013).

(13) “Half-titanocenes containing anionic ancillary donor ligands: Effective catalyst precursors for ethylene/styrene copolymerization”
K. Nomura, Catalysts, 3, 157-175 (2013).

2014
(14) “可視光(太陽光)促進有機金属触媒反応:フォトレドックス触媒と機能分担型二核錯体触媒系”
穐田宗隆, 小池隆司, 稲垣昭子,
有機合成化学協会誌, 72(5), 538-547 (2014).

(16) “A greener approach for synthesis of functinalized polyolefins by introducing reactive functionality into ethylene copolymers”
W. Apisuk, K. Tsutsumi, H.-J. Kim, D.-H. Kim, and K. Nomura
Green Sustain. Chem., 4, 133-143 (2014).

(17) “遷移金属錯体触媒によるオレフィン重合:オレフィン系高分子機能材料の精密合成”
野村琴広
触媒, 56, 300-305 (2014).

2015
(18) “Acyclic diene metathesis (ADMET) polymerization for precise synthesis of defect-free conjugated polymers with well-defined chain ends”
T. Haque, K. Nomura
Catalysts, 5, 500-517 (2015).

 

3.著書
2013
(15) “Recent progress in precise synthesis of polyolefins containing polar functionalities by transition metal catalysis”
K. Nomura, B. Kitiyanan
Advances in Organic Synthesis (Volume 3), Sarah A. Khan (Ed.), Bentham Science Publishers, pp174-194 (2013).

(16) “基礎から学ぶ有機化学”
伊與田正彦, 佐藤総一, 西長 亨, 三島正規
朝倉書店(2013).

(17) “環状オレフィン系ポリマーの精密合成のための高性能分子触媒”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 7, 44-48 (2013).

2014
(18) “Olefin polymerization by half-metallocene catalyst”
K. Nomura, J. Liu
Lecture Notes in Chemistry series “Organometallic Reactions and Polymerization”, K. Osakada (Ed.), Springer-Verlag, Berlin Heidelberg, 51-88 (2014).

(19) “Olefin polymerization by non-metallocene catalysts (Early transition metals)”
K. Nomura, W. Zhang
Lecture Notes in Chemistry series “Organometallic Reactions and Polymerization”, K. Osakada (Ed.), Springer-Verlag, Berlin Heidelberg, 89-117 (2014).

(20) “オレフィン重合・二量化のための高性能バナジウム錯体触媒”
野村琴広
「次世代ポリオレフィン総合研究」, 郷茂 夫, 寺野 稔(編), 8, 48-52(2014).

2015
(21) “ファインケミカル関連触媒の現状と展望”
野村琴広
触媒技術の動向と展望2015,触媒学会(編), 279-283 (2015).

(22) “Planar Cyclooctatetraenes and Related Ring Systems: Antiaromaticity and Applications”
T. Nishinaga
Chemical Science ofπ-Electron Systems, T. Akasaka, A. Osuka, S. Fukuzumi, H. Kandori, Y. Aso (Eds.) Springer: Heidelberg Germany, 47-67 (2015).

(23) “高性能オレフィン重合触媒の創製:Imidazolidin-2-iminato配位子を有するハーフチタノセン錯体の合成とエチレン重合触媒機能”
野村琴広
「次世代ポリオレフィン総合研究」, 郷茂 夫, 寺野 稔(編), 9, 22-26 (2015).

 

4.その他
2013
(6) “非環式ジエンメタセシス重合”
野村琴広
有機合成化学協会誌(解説), 71, 64 (2013).

(7) “開環メタセシス重合‐”
野村琴広
有機合成化学協会誌(解説), 71, 64 (2013).

(8) “化学実験での観察力・考察力の大切さ”
野村琴広
高校生・化学宣言Part6, 中沢 浩, 松坂裕之(監修), 207-208 (2013).

2015
(9) “研究室紹介‐北から南から- 首都大学東京理工学研究科分子物質化学専攻 有機化学研究室”
Organometallic News, 66-67 (2015).