2010-2012

1.原著論文
2010
(1) “Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing ferrocenyl group at 5-position”
T. Nishinaga, T. Aono, E. Isomura, S. Watanabe, Y. Miyake, A. Miyazaki, T. Enoki, H. Miyasaka, H. Otani, M. Iyoda
Dalton Trans., 39, 2293-2300 (2010).

(2) “Cyclic tetrathiophenes planarized by silicon and sulfur bridges bearing antiaromatic cyclooctatetraene core: Syntheses, structures, and properties”
T. Ohmae, T. Nishinaga, M. Wu, M. Iyoda
J. Am. Chem. Soc., 132, 1066-1074 (2010). Highlighted in Synfacts

(3) “1-Hexene polymerization by Cp*TiX2(O-2,6-iPr2C6H3) [X: Me, Cl] in the presence of MAO-, MMAO-modified carbonaceous materials”
M. Hofman, K. Nomura
J. Mol. Catal. A, 319, 85-91 (2010).

(4) “Highyl efficient dimerization of ethylene by (imido)vanadium complexes containing (2-anilidomethyl)pyridine ligand: Notable ligand effect toward activity and selectivity”
S. Zhang, K. Nomura
J. Am. Chem. Soc., 132, 4960-4965 (2010).

(5) “Mono- and bis-amidinate 2,6-xylylimido vanadium chlorides: synthesis, structure, and reactivity”
S. Aharonovich, M. Botoshansky, B. Tumanskii, K. Nomura, R. M. Waymouth, M. S. Eisen,
Dalton Trans., 39, 5463-5469 (2010).

(6) “Synthesis and properties of octithiophene dication sterically segregated by annelation with bicyclo[2.2.2]octene units”
T. Nishinaga, D. Yamazaki, M. Tateno, M. Iyoda, K. Komatsu
Materials, 3, 2037–2052 (2010).
Invited to the special issue “Conjugated Oligomers” Guest Editor Herbert Meier

(7) “Synthesis of bitetrathiafulvalenes with FeCl3-mediated homo-coupling of tetrathiafulvalenylmagnesium bromide and formation of nanostructures from bitetrathiafulvalenes having long alkylthio chains”
Y. Honna, E. Isomura, H. Enozawa, M. Hasegawa, M. Takase, T. Nishinaga, M. Iyoda
Tetrahedron Lett., 51, 679-682 (2010).

(8) “A facile, controlled synthesis of soluble star polymers containing a sugar residue by ring-opening metathesis polymerization (ROMP)”
H. Otani, S. Fujita, Y. Watanabe, M. Fujiki, K. Nomura
Macromol. Symp., 293, 53-57 (2010). Special symposium issue for the 18th International Symposium on Olefin Metathesis and Related Chemistry (ISOM XVIII)

(9) “Hetero-bimetallic complexes of titanatranes with aluminum alkyls: Synthesis, structural analysis, and their use in catalysis for ethylene polymerization”
Gurubasavaraj, M. P., K. Nomura
Organometallics., 29, 3500-3506 (2010).

(10) “Star-shaped oligothiphenes with unique photophysical properties and nanostructures”
T. Narita, M. Takase, T. Nishinaga, M. Iyoda, K. Kamada, K. Ohta
Chem. Eur. J., 16, 12108-12113 (2010). Inside cover

(11) “Biradical character of linear p-conjugated oligomer dications composed of thiophene, pyrrole and methylthio end-capping units”
Nishinaga, M. Tateno, M. Fujii, W. Fujita, M. Takase, M. Iyoda
Org. Lett., 12, 5374-5377 (2010).

2011
(12) “McMurry coupling of diformyldithienylacetylene: Synthesis of [24]-, [36]-, and [48]-annulenes composed of thiophene, acetylene, and ethylene units”
M. Iyoda, P. Huang, T. Nishiuchi, M. Takase, T. Nishinaga
Heterocycles, 82, 1143-1149 (2011).

(13) “Self-assembly and nanostructure formation of amphiphilic 4,5-bis(2-pyridylethynyl)tetrathiafulvalenes”
E. Isomura, T. Nishinaga, M. Iyoda
Supramol. Chem., 23, 304-309 (2011).

(14) “Ethylene polymerization by phenoxy substituted tris(pyrazolyl)borate Ti(IV) methyl complexes”
S. Hasumi, K. Itagaki, M. Fujiki, K. Nomura
Macromolecules, 44, 773-776 (2011).

(15) “1,2-C-H Activation of benzene promoted by (arylimido)vanadium(V)-alkylidene complexes: Isolation of the alkylidene, benzyne complexes”
S. Zhang, M. Tamm, and K. Nomura
Organometallics, 30, 2712-2720 (2011). Cover article

(16) “Olefin polymerization by half-titanocenes containing hapto2-pyrazolato ligands – MAO catalyst systems”
K. Nomura, H. Fukuda, S. Katao, M. Fujiki, H.-Y. Kim, D.-H. Kim, I. Saeed
Macromolecules, 44, 1986-1998 (2011).

(17) “Precise synthesis of poly(fluorene-2,7-vinylene)s containing oligo(thiophene)s at the chain ends: Unique emission properties by the end functinalization”
S. Kuwabara, N. Yamamoto, P. M. V. Sharma, K. Takamizu, M. Fujiki, Y. Geerts, K. Nomura
Macromolecules, 44, 3705-3711 (2011).

(18) “Effect of ligand substituents in olefin polymerisation by half-sandwich titanium complexes containing monoanionic iminoimidazolidide ligands – MAO catalyst systems”
K. Nomura, H. Fukuda, S. Katao, M. Fujiki, H.-J. Kim, D.-H. Kim, S. Zhang
Dalton Trans., 40, 7842-7849 (2011).

(19) “Unique reactivity od (arylimido)vanadium(V)-alkyl complexes with phenols: Fast phenoxy ligand exchange in the presence of vanadium(V)-alkyls”
K. Nomura, Y. Matsumoto
Organometallics, 30, 3610-3618 (2011).

(20) “Synthesis of (adamantylimido)vanadium(V)-alkyl complexes containing aryloxo ligands and their use as the catalyst precursors for ring-opening metathesis polymerization of norbornene and ring-opening polymerization of tetrahydrofuran”
K. Suzuki, Y. Matsumoto, K. Nomura
J. Organomet. Chem., 696, 4057-4063 (2011). Special issue (invited submission), Small molecule activation and catalysis using metal carbon multiple bonds dedicated to Prof. K. Caulton.

(21) “Synthesis and nanostructures of cyclic triphenylenetrimers having long alkyl and alkoxy side chains”
Y. Hanai, M. J. Rahman, J. Yamakawa, M. Takase, T. Nishinaga, M. Hasegawa, K. Kamada, M. Iyoda
Chem. Asian J., 6, 2940-2945 (2011).

(22) “Structural, optical, and electronic properties of a series of 3,4-propylenedioxythiophene oligomers in neutral and various oxidation state”
C. Lin, T. Endo, M. Takase, M. Iyoda, T. Nishinaga
J. Am. Chem. Soc., 133, 11339-11350 (2011).

(23) “Star-shaped pyrrole-fused tatrathiafulvalene oligomers: Synthesis and redox, self-assembling, and conductive properties”
M. Takase, N. Yoshida, T. Nishinaga, M. Iyoda
Org. Lett., 13, 3896-3899 (2011).

(24) “Synthesis and structural, electronic, optical and FET properties of thiophene-pyrrole mixed hexamers end-capped with phenyl and pentafluorophenyl groups”
T., Nishinaga, T. Miyata, M. Tateno, M. Koizumi, M. Takase, M. Iyoda, N. Kobayashi, Y. Kunugi
J. Mater. Chem., 21, 14959-14966 (2011).

2012
(25) “Precise synthesis of amphiphilic multiblock copolymers by combination of acyclic diene metathesis (ADMET) polymerization with atom transfer radical polymerization (ATRP) and click chemistry”
K. Nomura, M. M. Abdellatif
ACS Macro Lett., 1, 423-427 (2012).

(26) “Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials”
M. Takase, N. Yoshida, T. Narita, T. Fujio. T. Nishinaga, M. Iyoda
RSC Adv., 2, 3221-3224 (2012).

(27) “Synthesis and controlled self-assembly of covalently linked hexa-peri-hexabenzocoronene / perylene diimide dyads as models to study fundamental energy- and electron transfer processes”
L. F. Dössel, V. Kamm, I. A. Howard, F. Laquai, W. Pisula, X. Feng, C. Li, M. Takase, T. Kudernac, S. De Feyter, K. Müllen,
J. Am. Chem. Soc., 134, in press (2012).

(28) “Synthesis of oligo(thiophene) coated star shape ROMP polymers: Unique emission properties by the precise integration of functionality”
K. Takamizu, K. Nomura,
J. Am. Chem. Soc., 134, 7892-7895 (2012).

(29) “Ethylene dimerization/polymerization catalyzed by (adamantylimido)vanadium(V) complexes containing (2-anilidomethyl)pyridine ligands: Factors affecting the ethylene reactivity”
A. Igarashi, S. Zhang, K. Nomura
Organometallics, 31, 3575-3581 (2012).

(30) “Effect of cocatalyst in ethylene/styrene copolymerization by aryloxo-modified half-titanocene – cocatalyst systems for exclusive synthesis of copolymers under high styrene concentration conditions”
K. Nomura, N. Suzuki, D.-H. Kim, H. J. Kim
Macromol. Reac. Eng., 6, 351-356 (2012).

(31) “Chiral optofluidics: Gigantic circularly polarized light enhancement of all-trans-poly(9,9-di-n-octylfluoerene-2,7-vinylene) during mirror-symmetry-breaking aggregation by optically tuning fluidic media”
M. Fujiki, A. Jalilah, N. Suzuki, M. Taguchi, W. Zhang, M. M. Abdellatif, K. Nomura
RSC Adv., 2, 6663-6671 (2012).

(32) “Use of pyridine coated star shape ROMP polymers as the supported ligand for Ru-catalyzed chemoselective hydrogen transfer reductin of ketone”
K. Nomura, K. Tanaka, S. Fujita
Organometallics, 31, 5074-5080 (2012).

(33) “Ring-opening polymerization of THF by aryloxo-modified (imido)vanadium(V)-alkyl complexes and ring-opening metathesis polymerization by highly active V(CHSiMe3)(NAd)(OC6F5)(PMe3)2”
K. Nomura, K. Suzuki, S. Katao, Y. Matsumoto
Organometallics, 31, 5114-5120 (2012).

(34) “Ethylene copolymerization by half-titanocenes containing imidazolin-2-iminato ligands – MAO catalyst systems”
K. Nomura, H. Fukuda, W. Apisuk, A. G. Trambitas, B. Kitiyanan, M. Tamm
J. Mol. Catal. A: Chem., 363-364, 501-511 (2012).

(35) “Syntheses, molecular structures, and antiviral activities of 1- and 2-(20-deoxy-D-ribofuranosyl)cyclohepta[d][1,2,3]triazol-6(1H)-ones and 1-(20-deoxy-D-ribofuranosyl)cyclohepta[b]pyrrol-8(1H)-one”
T. Nakazawa, T. Ohmae, M. Fujimuro, M. Ito, T. Nishinaga, M. Iyoda
Tetrahedron, 68, 5368-5374 (2012).

(36) “Synthesis and structural analysis of phenoxy-substituted half-titanocenes with different anionic ligands,Cp*TiX(Y)(O-2,6-iPr2C6H3): Effect of anionic ligands (X,Y) in ethylene/styrene copolymerization”
K. Nomura, S. Pracha, K. Phomphrai, S. Katao, D.-H. Kim, H.-Y. Kim, N. Suzuki
J. Mol. Catal. A: Chem.,365, 136-145 (2012).

(37) “Effect of terminal aryloxo ligands in ethylene polymerization using titanatranes of the type, [Ti(OAr)(O-2,4-R2C6H2) -6-CH2}3N]: Synthesis and structural analysis of the hetero-bimetallic complexes of titanatranes with AlMe3”
Y. Takii, M. P. Gurubasavaraj, S. Katao, K. Nomura
Organometallics, 31, 8237-8248 (2012).

(38) “Self-Assembly, Chromic Properties, and Nanostructure Formation of Tetrathiafulvalene-fused Dodecadehydro[18]annulenes”
H. Enozawa, T. Takahashi, T. Nishinaga, T. Kato, M. Hasegawa, M. Iyoda
Bull. Chem. Soc. Jpn., 85, 1120–1137 (2012). Selected Papers

 

2.総説・解説
2010
(1) “Defect-Free共役ポリマーの環境調和型の精密合成新手法: オレフィンメタセシスを利用した立体特異性重合”
野村琴広
月刊ファインケミカル,シーエムシー出版,64-70 (2010).

(2) “Precise synthesis of polymers containing functional end groups by living ring-opening metathesis polymerization (ROMP): Efficient tools for synthesis of block/graft copolymers”
K. Nomura, M. M. Abdellatif
Polymer, 51, 1861-1881 (2010). Feature article, Invited submission

(3) “Syndiospecific styrene polymerization and ethylene/styrene copolymerization using falf-titanocenes: Ligand effects and some mechanistic aspects”
K. Nomura
Catal. Surv. Asia, 14, 33-49 (2010). Account, Invited submission

(4) “(Imido)vanadium(V)-alkyl, -alkylidene complexes exhibiting unique reactivity towards olefins and alcohols”
K. Nomura, W. Zhang
Chem. Sci., 1, 161-173 (2010). Mini Review, Invited submission

(5) “Recent studies on the aromaticity and antiaromaticity of planar cyclooctatetraene”
T. Nishinaga, T. Ohmae, M. Iyoda
Symmetry, 2, 76-97 (2010). Review invited to the special issue “Aromaticity and Molecular Symmetry”
Guest Editor Paul v. R. Schleyer

(6) “New approaches in precise synthesis of polyolefins containing polar functionalities by olefin copolymerizations using transition metal catalysts”
K. Nomura
J. Synth. Org. Chem., Jpn.(有機合成化学協会誌), 68, 1150-1158 (2010). Mini Review, Invited submission

(7) “新しいポリオレフィンの創製を指向した高性能チタン錯体触媒の設計”
野村琴広
触媒,52, 553-558 (2010). Feature Article, Invited submission

(8) “New approaches in precise synthesis of polyolefins containing polar functionalities by olefin copolymerizations using transition metal catalysts”
K. Nomura
J. Synth. Org. Chem., Jpn.(有機合成化学協会誌), 68, 1150-1158 (2010). Mini Review, Invited submission

2011
(9) “Design of new generation vanadium complex catalysts for precise olefin polymerization”
K. Nomura, S. Zhang
Chem. Rev., 111, 2342-2362 (2011). Review, Invited submission, a special issue, Frontiers in Transition Metal Catalyzed Reactions

(10) “(Imido)vanadium complexes as efficient catalyst precursors for olefin polymerization/oligomerization”
S. Zhang, K. Nomura
Catal. Surv. Asia, 15, 127-133 (2011). Mini Review, Invited submission, Special issue for TOCAT6/APCAT5

(11) “Half-titanocenes for precise olefin polymerisation: Effects of ligand substituents and some mechanistic aspects”
K. Nomura, J. Liu
Dalton Trans., 40, 7666-7682 (2011). Perspective, Invited submission, a themed issue dedicated to d0 organometallics in catalysis Cover article

2012
(12) “(Imido)vanadium-alkyl, alkylidene complexes exhibiting unique reactivities towards olefins, phenols, and benzene via 1,2-C-H bond activation”
K. Nomura
J. Chin. Chem. Soc., 59, 139-148 (2012). Mini Review, Invited submission中國化学会(台北) Cover picture

 

3.著書
2010
(1) “Copolymerization of ethylene with styrene: Design of efficient transition metal complex catalysts”
K. Nomura
Syndiotactic Polystyrene – Synthesis, Characterization, Processing, and Applications, J. Schellenberg (Ed.), John Wiley & Sons, Inc., pp. 60-91 (2010).

(2) “Fully conjugated nano-sized macrocycles: Syntheses and versatile properties”
M. Takase, M. Iyoda
Conjugated Polymer Synthesis – Methods and Reactions, Y. Chujo (Ed.), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 165-194 (2010).

(3) “レアメタル便覧” 高分子関連-重合反応
野村琴広
丸善(株),(著書分担)出版済

(4) “高性能バナジウム錯体触媒の設計・創製”
野村琴広
「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編), 4, 113-116 (2010).

2011
(5) “高分子合成反応の触媒”
野村琴広
「化学マスター講座<応用> 触媒化学」, 丸善出版(株), pp. 153-164 (2011).(著書分担)

(6) “オレフィンメタセシス(前周期遷移金属触媒)”
野村琴広
触媒調製ハンドブック, (株)エヌ・ティー・エス,pp. 338-343 (2011).(著書分担)

(7) “重合反応(メタロセン触媒)”
野村琴広
触媒調製ハンドブック, (株)エヌ・ティー・エス,pp. 365-369 (2011).(著書分担)

(8) “Precise synthesis of polyolefins containing polar functionalities by olefin coordination copolymerizations using group 4 metal catalysts”
K. Nomura, S. M. Abdellatif
Polymer Synthesis, Nova Science Publihsers, Inc., New York, USA, in press (2011).

(9) “錯体化合物辞典”
朝倉書店, (2011).(著書分担)

(10) “Conjugated Molecular Belts Based on 3-D Benzannulene Systems”
M. Iyoda, Y. Kuwatani, T. Nishinaga, M. Takase, T. Nishiuchi
Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry (Eds. Petrukhina, M. A. and Scott, L. T.), John Wiley & Sons, Inc. NJ, in press (2011).

(11) “新しい高性能オレフィン重合触媒の創製:MAOの要らないチタン錯体触媒の設計・創製”
野村琴広
「次世代ポリオレフィン総合研究」, 日本ポリオレフィン総合研究会(編), 5, 48-51 (2011).

2012
(12) “高分子合成触媒の研究における近年の変遷と今後の展望”
野村琴広
触媒技術の動向と展望2012,触媒学会(編),pp. 73-83 (2012). 触媒誌に転載 触媒, 54, 466-473 (2012).

(13) “Historical Stream, Trends and Outlook for Polymerization Catalysts”
K. Nomura
Special Edition for the 20th anniversary of publication of “Annual Survey of Catalytic Science and Technologies”,触媒学会(編),pp. 80-91 (2012).

(14) “ハーフチタノセン錯体触媒による効率エチレン/スチレン共重合”
野村琴広
「次世代ポリオレフィン総合研究」, 日本ポリオレフィン総合研究会(編), 6, 48-51 (2012).

 

4.その他
2010
(1) “高性能オレフィン重合チタン錯体触媒の設計・合成:MAOの要らない触媒設計”
野村琴広,Prabhuodeyara M. Gurubasavaraj,板垣浩司,藤木道也,蓮見真也
触媒, 52(2), 86-88 (2010).

2011
(2) “首都大学東京への異動に際して”
野村琴広
触媒, 53, 58 (2011). フォーラム執筆

(3) “TOCAT6/APCAT5参加報告(重合触媒関連)”
野村琴広, 福田紘也
触媒技術の動向と展望2011, 触媒学会(編), p338 (2011).

(4) “ファインケミカルズ合成触媒”
野村琴広
触媒,53, 321 (2011). 時評執筆

2012
(5) “研究室紹介”
野村琴広
触媒,54, 481 (2012).